After looking over part one I decided that I would cast these 190+3 characters in four parts. Part One was like the Marvel Knights. Part two is Avengers/S.H.I.E.L.D.
59)Captain America - Steve Rogers
-RYAN MCPARTLIN-(Chuck)
60)Bucky Barnes - Winter Soldier
-KEVIN ZERGES-(Gossip Girl)
61)Red Skull
-CHRISTOPH WALTZ-(Inglorious Bastards)
62)Baron Zemo
-HUGO WEAVING-(The Matrix, Lord of the Rings)
63)Baron Von Strucker
-RALPH FIENNES-(Harry Potter, Clash of the Titans)
64)Crossbones
-TOM HARDY-(Inception, Bronson)
65)Union Jack
-CALLUM BLUE-(Smallville)
66)Spitfire
-LAURA VANDERVOORT-(Smallville)
67)Iron Man - Tony Stark
-PATRICK DEMPSEY-(Made of Honor, Enchanted)
69)War Machine - James "Rhodey" Rhodes
-OMAR EPPS-(House)
70)Pepper Potts
-EVAN RACHEL WOODS-(True Blood)
71)The Mandarin
-CHOW YUN-FAT-(Pirates of the Carribean:At World's End)
72)Obidiah Stane
-JOHN MALKOVICH-(Red, Jonah Hex)
73)Crimson Dynamo
-OLEG TAKTAROV-(Predators, Alias)
74)Madame Masque
-SIENNA MILLER-(G.I. Joe:The Rise of Cobra)
75)Thor
-ALEXANDER SKARSGARD-(True Blood)
76)Jane Foster
-KERI RUSSELL-(August Rush, Mision Impossible III)
77)Lady Sif
-JULIA VOTH-(Bitch Slap)
78)Valkyrie
-RACHEL NICHOLS-(G.I. Joe:The Rise of Cobra)
79)Fandral
-HUGH DANCY-(Confessions of a Shopaholic)
80)Hogun
-COLLIN CHOW-(The Matrix, The Forbidden Kingdom)
81)Volstagg
-JOHN RHYS DAVIES-(Lord of the Rings)
82)Odin
-MALCOLM MCDOWELL-(Heroes, Doomsday)
83)Loki
-MATTHEW GOODE-(Watchmen)
84)Enchantress
-DIORA BAIRD-(Texas Chainsaw Massacre: The Begining)
85)Executioner
-BATISTA-(Smallville)
86)Hela
-FAIRUZA BALK-(The Craft)
87)Hulk - Bruce Banner
-SHARLTO COPLEY-(District 9)
88)Betty Ross
-REBECCA HALL-(Vicki Christina Barcelona)
89)Doc Samson
-MARK WHALBERG-(Max Payne, The Happening)
90)She Hulk - Jennifer Walters
-KAREN CLICHE-(Mutant X)
91)General Thunderbolt Ross
-DANNY HOUSTON-(X-Men Origins: Wolverine)
92)The Leader
-JOSEPH FIENNES-(Flash Forward)
93)Abomination
-DWAYNE "THE ROCK" JOHNSON-(The Scorpion King)
94)Absorbing Man
-VINNIE JONES-(X-Men: The Last Stand)
95)Ant-Man - Henry "Hank" Pym
-PATRICK WILSON-(Watchmen)
96)Wasp - Janet Van Dyne
-GEMMA ARTERTON-(Clash of the Titans)
97)Vision
-PAUL BETTANY-(Legion)
98)Ms.Marvel - Carol Danvers
-CHARLIZE THERON-(Hancock)
99)Tigra
-EVA MENDES-(The Spirit)
100)Spider-Woman - Jessica Drew
-KATE BECKINSALE-(Underworld)
101)Wonder Man
-ERIC DANE-(X-Men: The Last Stand)
102)Black Widow - Natasha Romanoff
-EMILY BLUNT-(The Devil Wears Prada)
103)Black Widow - Yelena Belova
-YVONNE STRAHVOSKI-(Chuck)
104)Hawkeye - Clint Barton
-CHRIS PINE-(Star Trek)
105)Mockingbird
-KRISTEN BELL-(Veronica Mars)
106)Nick Fury
-GEORGE CLOONEY-(Ocean's Eleven)
107)Dum Dum Dugan
-WOODY HARRELSON-(No Country for Old Men, Zombieland)
108)Maria Hill
-JESSICA ALBA-(Dark Angel, Fantastic Four)
109)Sharon Carter
-ALI LARTER-(Resident Evil, Heroes)
110)Viper
-ELIZA DUSHKU-(Buffy the Vampire Slayer, Dollhouse)