Paolo Rivera is an Eisner awarding Marvel comic book artist best known for his work on the origin, one-short series, Mythos and an early 2000's run on Spider-Man with Mark Waid. Here's a full run down of past cast and crew posters and the artists behind them.
Note - Cast and crew only posters started with Thor (2011), as far as the public knows .
Thor (2011) - Olly Moss
Captain America: The First Avenger (2011)- Paolo Rivera
The Avengers (2012) - ?
Iron Man 3 (2013) - Paolo Rivera
Thor: The Dark World (2013) - Olly Moss
Captain America: The Winter Soldier (2014) - Paolo Rivera
Guardians of the Galaxy (2014) - Tyler Stout
Avengers: Age of Ultron (2015) - Tyler Stout
Ant-Man (2015) - ?
Captain America: Civil War (2016) - Paolo Rivera
And here's some preliminary, rough sketches Rivera did before settling on the final compositon.
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Captain America: Civil War” picks up where “Avengers: Age of Ultron” left off, as Steve Rogers leads the new team of Avengers in their continued efforts to safeguard humanity. After another international incident involving the Avengers results in collateral damage, political pressure mounts to install a system of accountability and a governing body to determine when to enlist the services of the team. The new status quo fractures the Avengers while they try to protect the world from a new and nefarious villain.