Ever since the cancellation of the cartoon back in late 2009, fans were mostly displeased with Disney's approach to the wall crawler, as arguably the currently running Ultimate Spider-Man is aimed at a younger audience, and at times ignores the original source material from the comics.
Fans have been pleading Sony for years to make season 2 of The Spectacular Spider-Man available as a complete season DVD set, and instead Sony have combined the two seasons as a complete series set on Blu-ray!
It's set to be released on the 22nd of April in the US, and its now available to pre-order on Amazon.com
http://www.amazon.com/gp/product/B00IGVJH0E/ref=as_li_ss_tl?ie=UTF8&camp=1789&creative=390957&creativeASIN=B00IGVJH0E&linkCode=as2&tag=dnf03-20
U.K fans can also finally gain access to the season one DVD that was released in the states a few years back,
http://www.amazon.co.uk/The-Spectacular-Spider-Man-Complete-Season/dp/B00HQAKVMO/ref=sr_1_11?ie=UTF8&qid=1393275844&sr=8-11&keywords=spectacular+spidermanbut
No word on a complete Blu-ray set in the U.K however.